The introduction of water impurities to the boiler can lead to higher conductivity, increasing corrosion potential. <<60FB01378AEBC7448D78B6BE7EF2A14B>]>> 148 37 0000000016 00000 n In addition, heavy mineral deposits restrict heat transfer. 0000020372 00000 n A chemical-reducing agent can lower dissolved oxygen levels to prevent or minimize corrosion within the boiler and turbines. NlV,/94/y?)\9VtJ9hspeP"dY!Gu+[&L 3. Sentry can provide insight on the best solution for your plant, including SWAS and single line options. 0000008468 00000 n 0000001907 00000 n Phosphate corrosion is the name given to attack involving phosphate compounds having unique wastage morphologies and associated corrosion products and deposits. {open_quotes}OH{close_quotes} treatment is simpler. 0000003581 00000 n Congruent control was devised to prevent the formation of free caustic by feeding orthophosphates so as to maintain a boiler water sodium to phosphate ratio in a range where theory surmised free caustic could not form. Precipitation was caused by inadequate heat flow inducing a departure from nucleate boiling (DNB), steam blanketing, and deposits. As Upgrading feed rates have increased, the volume flow rate, and properties of the streams have changed to such extent that the boilers have suffered severe reliability problems due to the new, and adverse fireside conditions. John Powalisz, Director of International Sales, is dedicated to sharing his technical expertise and knowledge of sampling equipment and systems in power plants, refineries, chemical and food processing facilities garnered from more than 19 years with the company. As the heart of the plant, these boilers are crucial to efficient energy creation. xb```f``Id`e``5bd@ A6 daS$>nxtgbr Industrial boiler water treatment helps protect low-pressure steam generators often found in co-generation plants. While he is well-versed in all Sentry products and applications, he is particularly focused on the food and beverage and power generation markets as well as emerging market development. }WjFGyIW=l+2|H!2]#nGK2TkqDt:?l7pu^fQ;Osg*={R_keOP'xRg8X8]!OZ,te?/+?C(zMf'nx#u Y'.ag@"DHar(3H|J/clia n(+g3' K^>mOX3+su;H*j!aV&d0 *{MAQ@Am/bDWx y?Xu0'^5WZ3ijxmV70)?JKnT/VZv3Lp'Q0\8 gV-M*NsSB.zA0:e"79=%q:VJ?}(' E8@;? (L20'ui% [ 0!!(&M990Zus=73lVe7U@s"@N.(t30K i& v % cUd %PDF-1.4 % Its also recommended that sludge conditioners using water-soluble polymers can help keep solids in suspension by a combination of dispersion, crystal modification and sequestration, in addition to phosphate treatment. hTP1n0 Theyre often delivered via injection equipment, such as atomizers or sample quills. 0000102220 00000 n Many medium- to high-pressure boiler systems, including carbon steel boilers, suffer from corrosion and impurities. TrxzE4P`Qbr%4qIkV:{JhNMti:oNs+|]$ 0000092537 00000 n Chelants, such as ethylenediaminetetraacetic acid (EDTA), sometimes can be used to bind with metals to keep them suspended. 148 0 obj <> endobj Selective pearlite corrosion and possible, incipient hydrogen damage were associated. 0000004468 00000 n Problems of control and corrosion with PT led to a search for alternative methods of conditioning in other countries. treatment over all volatile treatment (AVT), include a higher tolerance to chloride in the boiler water and a reduced risk of acid attack. Analysis results, conclusions, and recommendations to the plant are discussed. __^% 89L'v1$6+0~nc4eD# These factors must be evaluated carefully for each plant, as a standardized approach can lead to serious problems. surfaces of the water wall tubes. 0000002041 00000 n Micro-Raman spectroscopy was used for the first time to confirm the presence of maricite when investigating the root cause of generating bank tube failures. %%EOF Additionally, corrosion and cooling/heating equipment can help maintain purified water with little contaminants from materials. Theoretically, the condensate should be clean water. hXr}W#"G_T[[%2y#1pt H$*$fzO>wPoe(BY"?)Kd!4E&7}&@,+!/DT'K^;&Ne,_W)Y$-s- 0000092769 00000 n John has worked with clients worldwide to help them to comply with regulations and optimize processes by applying proper sampling hardware and techniques. 0000002982 00000 n Boiler water can be treated with several agents, including a phosphate/polymer combination, polymers alone, and (rarely) chelating agents. Phosphate corrosion is the name given to attack involving phosphate compounds having unique wastage morphologies, associated corrosion products and deposits. 0000006984 00000 n 0000060263 00000 n Unfortunately, conventional congruent control did not take into account the interaction of phosphate compounds with various deposits and corrosion, The waste gas streams from upgrading processes pass as primary energy sources to two CO boilers. Many failures were attributed to ``free`` caustic generated by the nonstoichiometric precipitation of various phosphate compounds on boiler surfaces. This produces unique wastage morphologies and characteristic corrosion products of NaFePO[sub 4]. Unfortunately, conventional congruent control did not take into account the interaction of phosphate compounds with deposits and corrosion products, including iron oxides on boiler tube surfaces, and corrosion continued. 0000007500 00000 n These materials include scavenger chemicals or corrosion inhibitors injected into the boiler or boiler feedwater. 0000011162 00000 n Corrosion continued to occur even when sodium to phosphate-pH control ranges were maintained according to theory. ,BO:|AP%hiBhR feNH >d* Mjo As operating pressures have increased, the frequency of corrosion-related failures in phosphate-treated boilers has also increased. 2. A Steam and Water Analysis System (SWAS) comprised of properly selected sample conditioning equipment and on-line instrumentation is key to controlling and monitoring your system treatment regime. 0000003120 00000 n hbspt.cta._relativeUrls=true;hbspt.cta.load(532305, '1466073b-4775-4785-b94a-81779404607c', {"useNewLoader":"true","region":"na1"}); Topics: The engineered changes required to correct the combustion and thermal hydraulic problems are described, as well as the rationale for introducing equilibrium phosphate treatment as the boiler water chemistry control corrective action. :x&L:~i*xY(hf[TdC Lx:?2h#9m$AH|-6Ut[mZDf&XZ= rm6t.l"iFk(9[;nD|n`uSZaDbau{ lqS6@`'U2 Hn cs+l0Fpo: However, corrosion occurred in the new high pressure plant, due to hydrogen damage and caustic gouging. Four finned, convection tubes from a 450 psi (3,1 MPa) waste-heat boiler at a chemical processing plant were examined to determine the cause of severe internal gouging corrosion. products, including iron oxides on boiler tube surfaces. 0 All of these contaminants negatively affect the feedwater systems, boilers and turbines in the plant, potentially causing unnecessary downtime and equipment damage. 0000019918 00000 n Boiler water treatment. 1. Steam & Water. xref ;{\di&s1c->D.uxj+-nj2,|NAYCl g?,@z.vC8hS{6Um]=pfr:S+&Skq6Q^ {Zu7Kf endstream endobj 158 0 obj <> endobj 159 0 obj <> endobj 160 0 obj <> endobj 161 0 obj <>stream Chemical treatment in industrial boilers can be complicated due to: Process steam carries heat from cogeneration plants. 0000002361 00000 n Phosphate attack as caustic corrosion in high-pressure boiler tubes, 360105* - Metals & Alloys- Corrosion & Erosion. startxref Condensate makeup is not required to be demineralized which can cause buildup of these impurities in boilers. g,.%E\#/1K@Cb@R@vS"1EQI7D53et+S+P*q4..bkD6J]Et]#%@ghD,VyUu aI1zULJ @CI%Aah 8:: \q,!+HL4(HB3]G![~s!1]A[)Y+(U. Some sodium hydroxide needs to be present in the boiler water to achieve the full benefits of {open_quotes}OH{close_quotes} treatment, but the concentration has to be strictly limited to reduce the risk of caustic gouging in the boiler, carry-over into the steam and damage to superheaters, reheaters and turbines. But in practice, the processing system introduces contaminants into the liquid stream and condensate return, including iron, copper, ammonia, magnesium, calcium and organic carbon. Congruent phosphate control was derived to prevent the formation of free caustic by feeding orthophosphates to maintain a boiler water sodium-to-phosphate ratio at which theory surmised free caustic could not form. EUF]+s&. Once a treatment is chosen, monitoring chemistry Is the best way to ensure the treatment is working appropriately. 0000008167 00000 n The paper also discusses the use of the latest Electrical Power Research Institute guidelines for failure mechanism identification in boiler tubes and for monitoring cycle chemistry. 0000088218 00000 n Film-forming substances (FFS). 0000088443 00000 n If impurities enter the boiler feedwater or corrosion develops inside the boiler, equipment can be damaged, the plant can experience unexpected downtime, and energy creation can be extremely ineffective. 0000092985 00000 n FFS are a range of corrosion-inhibiting products for boiler chemistry, including film-forming amines (FFAs). 0000002228 00000 n Caustic attack, resulting from excessive gas-side heat flux relative to the internal coolant flow rate, was found. Phosphate treatment programs use blends of tri- di- and monosodium phosphate for pH control as well. 0000007118 00000 n Phosphate corrosion in high pressure boilers, CO boiler reliability: examination of failure mechanisms, root causes, corrective actions and monitoring required, Phosphate corrosion in high-pressure boilers, Caustic corrosion of convection tubing in a waste-heat boiler. This steam delivers the latent heat to the manufacturing process, leaving liquid condensate. 0000001036 00000 n The benefits of {open_quotes}OH{close_quotes}. This is achieved by continuous monitoring the feedwater, boiler water and steam. 0000101755 00000 n Maricite is one of the definitive corrosion products resulting from acid phosphate corrosion. Any Application, Heat flux rates have increased in critical sections of the boiler with consequent disruption in thermal hydraulic flow in water and steam circuits. Sludge conditioners can also help keep iron particles in suspension for subsequent blowdown. 0000001822 00000 n It is still necessary to limit the chloride in the boiler water to prevent hydrogen damage. 0000003544 00000 n 0000003867 00000 n Chemical-reducing substances. -:Hv3tDbJ$8 :# 'GP`{Wu D;=4iDi-)!7!g Trisodium phosphate (Na3PO4), also known as TSP, is a common boiler water conditioning chemical that establishes moderately alkaline conditions in the boiler to minimize corrosion and reduce scaling where hardness ingress occurs. Compared with PT, it avoids phosphate hide-out and problems with monitoring and control. This paper discusses the use of computational fluid dynamic simulation and other techniques to assess water and fireside conditions for the original, current, and future operating conditions (prior to and post boiler design modifications). o% G3fx6si9h.-rj/I[?H0ft*$=t:@w&)Q R,1GobL~+AX-2J(ard0o45BWZgG,(msiC\h N ~Q[&/#FN|[n-N gOukcz&.V=38(O2gn3!om=h$Q%^DI}%kQfvL9LzU !j ey&g/; Phosphate treatments have been used in boilers for more than 70 years. This is referred to as phosphate corrosion. For example, in steam generators that commonly operate at or below 600 psi, uncatalyzed or catalyzed sodium sulfite (Na2SO3) is a non-volatile oxygen scavenger that adds inorganic dissolved solids to the feedwater. However, chelants should be used only with well-deaerated feedwater, excellent pre-treatment control and low feedwater iron concentrations. Its critical to limit impurities and corrosion in a boiler system to maximize boiler output and prevent these challenges. YX\5wb ,=#P:7FzQA|LXUX&cX^dEI?C/?la`%y;f=n~5Z,|*3i:=nG(^|*yv0tOFNv^CrxH 0000007723 00000 n High concentrations of sodium phosphate and sodium hydroxide were used for conditioning drum boilers in the 1950`s. Caustic corrosion produces well-defined depressions or gouges, as does phosphate attack at lower sodium-to-phosphate ratios. As operating pressures increased, the frequency of corrosion-related failures in phosphate-treated boilers also increased. trailer 0000078279 00000 n FFS inhibit corrosion by forming a very thin, non-wetable film on the surface of power plant equipment, which acts as a barrier between the metal surface and the water/steam phase to help reduce corrosion. Limiting chloride ingress and the use of low concentrations of sodium hydroxide ({open_quotes}OH{close_quotes} treatment) was developed and now is used successfully for more than 50,000 MWe of plant. The boiler tubes, made of ASTM A 178 GrC, failed by precipitation of the phosphates used for the chemical treatment of the boiler water, coupled with contamination of the condensate with alkaline salts. 184 0 obj <>stream endstream endobj 149 0 obj <> endobj 150 0 obj <> endobj 151 0 obj <>/Font<>/ProcSet[/PDF/Text]/ExtGState<>>> endobj 152 0 obj <> endobj 153 0 obj <> endobj 154 0 obj <> endobj 155 0 obj <> endobj 156 0 obj [/ICCBased 168 0 R] endobj 157 0 obj <>stream Departure from nucleate boiling (DNB) and steam blanketing in generating bank tubes have resulted, causing treatment chemicals to precipitate, deposit, and react on the internal. An example is a 1,300 psi (9 MPa) and 930 F (500 C) boiler. The chemical guidelines for {open_quotes}OH{close_quotes} treatment adopted overseas are reviewed, together with the evidence gained from operating plant, the problems that occurred and how these were overcome, EPRI guidelines are proposed for coal fired plant. Organic cycle chemistry based on FFS is being increasingly employed as an alternative to conventional treatment programs because they inhibit corrosion while maintaining clean heat transfer surfaces. 0000004136 00000 n Some boiler-tube failures attributed to caustic gouging actually have been caused by reaction of sodium phosphate species with boiler tube steel, boiler tube oxides, or both. Industrial steam plants and combined steam and power facilities, also known as cogeneration plants, commonly use boilers to provide high-quality steam and electric power. Choosing the appropriate treatment depends on a variety of factors, including boiler design and pressure, the effectiveness and reliability of the makeup water treatment system and the risk of impurity ingress and iron oxide carryover from condensate return. 0000020167 00000 n Contact us at +1-262-567-7256, orcomplete our online contact formfor more information. 0000102008 00000 n 0000087950 00000 n This led to sodium hydroxide being abandoned in the USA in favour of phosphate treatment (PT). 0000008024 00000 n The Importance of Industrial Boiler Water Treatment, Sentry can provide insight on the best solution for your plant, including, Understanding the Challenges in HRSG Water and Steam Monitoring, The Advantages of Chlorine Dosing to Control Biofilm, Impurity ingress from steam feed and condensate return systems, Impurities, such as hardness, from inadequate makeup water treatment system performance, Condensate return system corrosion that damages piping and equipment, and sends iron oxide corrosion to the boiler, which can deposit and reduce effective heat transfer. 0000004214 00000 n

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